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ChemInform Abstract: Enantiospecific Total Synthesis of (-)-D-Noviose.

โœ Scribed by W. M. PANKAU; W. KREISER


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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Enantiospecific Total Synthesis of (+)-2-Pupukeanone. -The first enantiospecific total synthesis of 2-pupukeanone (X) starting from readily available (R)-carvone (I) is described. Key step in the synthetic sequence is the construction of the tricyclic isotwistane carbon framework via 5-exo-trig rad