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ChemInform Abstract: Enantioselective Total Synthesis of (-)-Triptolide, (-)-Triptonide, (+)-Triptophenolide, and (+)-Triptoquinonide.

โœ Scribed by Dan Yang; Xiang-Yang Ye; Ming Xu


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective To
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Enantioselective Total Synthesis of (+)-Isoboonein. -Starting from the known optically active diol (I), derived via an asymmetric Diels-Alder reaction of dimethyl fumarate with cyclopentadiene, the key intermediate (II) is synthesized via a known approach applied to the racemic series. Further sele