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ChemInform Abstract: Enantioselective Synthesis of α-Branched α-Amino Acids with Bulky Substituents.

✍ Scribed by A. STUDER; D. SEEBACH

Book ID
112022478
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
26
Category
Article
ISSN
0931-7597

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Enantioselective synthesis of α-branched
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Enantioselective Synthesis of α-Amino Acids from Nitroalkenes. -Careful oxidation of the addition products (I) of (R)-4-phenyl-2-oxazolidine and nitroalkenes yields the acids (II) which can be easily cleaved to D-α-amino acids of high optical purity.