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ChemInform Abstract: Enantioselective Synthesis of α-Amino Acids in Chiral Reverse Micelles.

✍ Scribed by W. WU; Y. ZHANG

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Enantioselective Synthesis of α-Amino Acids in Chiral Reverse Micelles.

-The asymmetric induction depends on the temperature as well as on alkyl chain length and structure of the surfactants used. -(WU,

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Enantioselective Synthesis of α-Amino Acids from Nitroalkenes. -Careful oxidation of the addition products (I) of (R)-4-phenyl-2-oxazolidine and nitroalkenes yields the acids (II) which can be easily cleaved to D-α-amino acids of high optical purity.