ChemInform Abstract: Enantioselective Synthesis of the Papulacandin Ring System: Conversion of the Mannose Diastereoisomer into a Glucose Stereoisomer.
β Scribed by Devan Balachari; George A. O'Doherty
- Book ID
- 101911601
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 31 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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A Facile Entry into the Ring System of Sativene. -Careful bromination of the diketone (I) allows the synthesis of the dibromides (II) and (III) or corresponding tribromide (IV). Their DBU-mediated dehydrobromination leads to tricyclic compounds of which (V) and (VII) have the same carbon skeleton a