𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Enantioselective Synthesis of Optically Active Alkylphosphonates via Rh-Catalyzed Asymmetric Hydrogenation of β-Substituted α,β-Unsaturated Phosphonates.

✍ Scribed by Zheng-chao Duan; Lian-zhi Wang; Xin-jian Song; Xiang-ping Hu; Zhuo Zheng

Book ID
115553380
Publisher
John Wiley and Sons
Year
2012
Weight
36 KB
Volume
43
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Cu-catalyzed asymmetric conjugate reduct
Cu-catalyzed asymmetric conjugate reduction of β-substituted α,β-unsaturated phosphonates: an efficient synthesis of optically active β-stereogenic alkylphosphonates
✍ Zheng-Chao Duan; Xiang-Ping Hu; Dao-Yong Wang; Sai-Bo Yu; Zhuo Zheng 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 249 KB

A series of chiral alkylphosphonates bearing b-stereogenic center were synthesized in good enantioselectivities (up to 95% ee) via the CuH-catalyzed asymmetric conjugate reduction of b-substituted a,b-unsaturated phosphonates under optimal conditions using Cu(OAc) 2 ÁH 2 O as the copper source, (R)-