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ChemInform Abstract: Enantioselective Synthesis of Hydroxy-Substituted DBN-Type Amidines as Potential Chiral Catalysts.

โœ Scribed by Martin Ostendorf; Sandor van der Neut; Floris P. J. T. Rutjes; Henk Hiemstra


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
31
Category
Article
ISSN
0931-7597

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Enantioselective Synthesis of Hydroxy-Su
โœ Martin Ostendorf; Sandor van der Neut; Floris P. J. T. Rutjes; Henk Hiemstra ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 403 KB

The synthesis and X-ray crystal structures of three meso-imide and was functionalized through N-acyliminium ion chemistry. The hydroxy groups were introduced by enantiopure hydroxy-substituted amidines of the DBN-type are described. The key starting material, a 5-ozonolysis or reduction. Preliminary