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ChemInform Abstract: Enantioselective Syntheses of Dopaminergic (R)- and (S)-Benzyltetrahydroisoquinolines.

✍ Scribed by Nuria Cabedo; Inmaculada Andreu; M. Carmen Ramirez de Arellano; Abdeslam Chagraoui; Angel Serrano; Almudena Bermejo; Philippe Protais; Diego Cortes

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Enantioselective Syntheses of Tussilagine and Isotussilagine. -LDA-mediated addition of chiral benzylamine (I) to methyl pyruvate (II) generates the separable diastereomers (III) and (IV). The latter can be conveniently transformed to tussilagine (VIII) by lactam formation and following Mitsunobu r