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ChemInform Abstract: Enantioselective Reduction of Oxime Ethers with Borane Catalyzed by Polymer-Supported 2-Piperazinemethanol.

✍ Scribed by Shinichi Itsuno; Takeshi Matsumoto; Daisuke Sato; Tsutomu Inoue

Publisher
John Wiley and Sons
Year
2000
Weight
27 KB
Volume
31
Category
Article
ISSN
0931-7597

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Quantum chemical study on enantioselecti
Quantum chemical study on enantioselective reduction of keto oxime ether with borane catalyzed by oxazaborolidine. Part 1. Structures of catalyst–borane–keto oxime ether adducts
✍ Ming Li; Wenxu Zheng; Feng Yang; Anmin Tian πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 267 KB πŸ‘ 1 views

In the present work, quantum chemical computations of the enantioselective reduction of keto oxime ether with borane catalyzed by chiral oxazaborolidine are performed by means of the Hartree-Fock and the density functional methods. The structures of oxazaborolidine, oxazaborolidine-borane adduct, an