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ChemInform Abstract: Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)ReV—Oxo Complexes.

✍ Scribed by Kristine A. Nolin; Richard W. Ahn; Yusuke Kobayashi; Joshua J. Kennedy-Smith; F. Dean Toste

Publisher
John Wiley and Sons
Year
2010
Weight
100 KB
Volume
42
Category
Article
ISSN
0931-7597

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Enantioselective Reduction of Ketones an
Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)ReV–Oxo Complexes
✍ Kristine A. Nolin; Richard W. Ahn; Yusuke Kobayashi; Joshua J. Kennedy-Smith; F. 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 324 KB 👁 1 views

## Abstract The development and application of chiral, non‐racemic Re^V^–oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer–Schuster

ChemInform Abstract: Enantioselective Bo
ChemInform Abstract: Enantioselective Borane Reduction of Ketones Catalyzed by Chiral Lanthanum Alkoxides.
✍ F.-Y. ZHANG; C.-W. YIP; A. S. C. CHAN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

Enantioselective Borane Reduction of Ketones Catalyzed by Chiral Lanthanum Alkoxides. -The enantioselective reduction of simple unfunctionalized ketones (I) is achieved by borane in the presence of a preformed catalyst from (R)-binaphthol and lanthanum triisopropoxide. -(ZHANG,