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ChemInform Abstract: Enantioselective Organocatalytic Indole Alkylations. Design of a New and Highly Effective Chiral Amine for Iminium Catalysis.

✍ Scribed by Joel F. Austin; David W. C. MacMillan

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A New Planar Chiral
ChemInform Abstract: A New Planar Chiral Bisphosphine Ligand for Asymmetric Catalysis: Highly Enantioselective Hydrogenations under Mild Conditions.
✍ P. J. PYE; K. ROSSEN; R. A. REAMER; N. N. TSOU; R. P. VOLANTE; P. J. REIDER πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 1 views

Mild Conditions. -A new chiral bis-phosphine ligand with a paracyclophane backbone is prepared and used as ligand in Rh-catalyzed hydrogenations of dehydroamino acid esters such as (I) with high enantioselectivity. -(PYE, P.