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ChemInform Abstract: Enantioselective Organocatalysis Involving Iminium, Enamine, Somo, and Photoredox Activation

✍ Scribed by Allan J. B. Watson; David W. C. MacMillan

Publisher
John Wiley and Sons
Year
2011
Weight
18 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract The first enantioselective α‐benzylation of aldehydes with electron‐deficient aryl and heteroaryl substrates proceeds in the presence of a chiral imidazolidinone organocatalyst, an iridium photoredox catalyst, and in the presence of household fluorescent light.