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ChemInform Abstract: Enantioselective Nucleophilic Addition of Trimethylsilylacetylene to N-Phosphinoylimines Promoted by C2-Symmetric Proline-Derived β-Amino Alcohol.

✍ Scribed by Shaoqun Zhu; Wenjin Yan; Bin Mao; Xianxing Jiang; Rui Wang

Publisher
John Wiley and Sons
Year
2010
Weight
53 KB
Volume
41
Category
Article
ISSN
0931-7597

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## Abstract A new synthetic methodology for the preparation of optically active propargylamines is described. The alkynylation of aromatic, heteroaromatic, aliphatic and α,β‐unsaturated __N__‐(diphenylphosphinoyl)imines was investigated by using diethylzinc and a proline‐derived β‐amino alcohol. __

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v