ChemInform Abstract: Enantioselective Hydrogenation of N—H Imines.
✍ Scribed by Guohua Hou; Francis Gosselin; Wei Li; J. Christopher McWilliams; Yongkui Sun; Mark Weisel; Paul D. O'Shea; Cheng-yi Chen; Ian W. Davies; Xumu Zhang
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 28 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Iridium-Catalyzed Enantioselective Hydrogenation of Imines in Supercritical Carbon Dioxide. -Supercritical CO 2 is used as an environmentally benign alternative solvent for the enantioselective hydrogenation of prochiral imines. Main advantages of this reaction medium are the low catalyst loading,