ChemInform Abstract: Iridium-Catalyzed Enantioselective Hydrogenation of Imines in Supercritical Carbon Dioxide.
β Scribed by Sabine Kainz; Axel Brinkmann; Walter Leitner; Andreas Pfaltz
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
β¦ Synopsis
Iridium-Catalyzed Enantioselective Hydrogenation of Imines in Supercritical Carbon Dioxide.
-Supercritical CO 2 is used as an environmentally benign alternative solvent for the enantioselective hydrogenation of prochiral imines. Main advantages of this reaction medium are the low catalyst loading, efficient product isolation and catalyst recycling. The substrate is found to be of key importance for solubilizing the catalytically active species. Good levels of asymmetric induction are observed only with catalysts containing
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v