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ChemInform Abstract: Enantioselective Hydrogenation of Enones with a Hydroformylation Catalyst.

✍ Scribed by Caroline J. Scheuermann; Christoph Jaekel


Publisher
John Wiley and Sons
Year
2009
Weight
28 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Enantioselective Hydrogenation of Enones
✍ Caroline J. Scheuermann née Taylor; Christoph Jaekel 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB 👁 1 views

## Abstract Use of a typical rhodium precatalyst for hydroformylation results in the enantioselective hydrogenation of cyclic enones with up to 90% __ee__. Extensive screening of chiral ligands reveals the simple ligand Chiraphos as the best ligand, so far. The hydrogenation shows high chemoselecti