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ChemInform Abstract: Enantioselective Catalytic α-Alkylation of Aldehydes via an SN1 Pathway.

✍ Scribed by Adam R. Brown; Wen-Hsin Kuo; Eric N. Jacobsen

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective α-
ChemInform Abstract: Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis.
✍ Hui-Wen Shih; Mark N. Vander Wal; Rebecca L. Grange; David W. C. MacMillan 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 52 KB 👁 1 views

## Abstract The first enantioselective α‐benzylation of aldehydes with electron‐deficient aryl and heteroaryl substrates proceeds in the presence of a chiral imidazolidinone organocatalyst, an iridium photoredox catalyst, and in the presence of household fluorescent light.