ChemInform Abstract: Enantioselective Catalysis. Part 18. The Influence of Non-Coordinated Stereocenters on the Enantioselective Hydrogenation.
β Scribed by U. NAGEL; C. ROLLER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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The Effects of N-Methylation on the Enantioselectivity of Catalysis by cyclo[(R)-His-(R)-Phe]. -Cyclo[(R)-His-(R)-Phe] and cyclo[(S)-His-(S)-Phe] are useful catalysts for the enantioselective formation of cyanohydrins from aldehydes and HCN. Their N-methylated derivatives, however, afford little or