ChemInform Abstract: Enantioselective Allylation of N-(Trimethylsilyl)benzaldehyde Imine Using Polymer-Supported Chiral Allylboron Reagents.

✍ Scribed by A. A. EL-SHEHAWY; M. Y. ABDELAAL; K. WATANABE; K. ITO; S. ITSUNO

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199743041

✦ Synopsis

1997 stereochemistry stereochemistry (general, optical resolution) O 0030

43 -041

Enantioselective Allylation of N-(Trimethylsilyl)benzaldehyde Imine Using Polymer-Supported Chiral Allylboron Reagents.

-Both polymers (I) and (II) are found to be excellent chiral ligands in the title reactions. Compared to the monomeric camphor analogues, yields and e.e. values can be improved.