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ChemInform Abstract: Enantio- and Diastereoselective Synthesis of (E)-1,5-syn-Diols: Application to the Synthesis of the C(23)—C(40) Fragment of Tetrafibricin.

✍ Scribed by Jeremy Kister; Philippe Nuhant; Ricardo Lira; Achim Sorg; William R. Roush

Publisher
John Wiley and Sons
Year
2011
Weight
41 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Total Synthesis of
ChemInform Abstract: Total Synthesis of Milbemycin E: Resolution of the C(1)-C(10) Fragment and Final Assembly.
✍ P. G. STEEL; O. S. MILLS; E. R. PARMEE; E. J. THOMAS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Total Synthesis of Milbemycin E: Resolution of the C(1)-C(10) Fragment and Final Assembly. -Resolution of the cyclohexanone (I) is the starting process in the preparation of title compound (VI). Key step is the coupling of butenolide (II) with phosphonium salt (III) (both prepared in the preceding p