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ChemInform Abstract: Efficient Synthetic Method for the Preparation of Allyl- and Propargyl-Epoxides by Allylation and Propargylation of α-Haloketones with Organozinc Reagents.

✍ Scribed by Jie Pan; Min Zhang; Songlin Zhang


Book ID
112045361
Publisher
John Wiley and Sons
Year
2012
Weight
42 KB
Volume
43
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Simple Synthetic Me
✍ I. SHIBATA; S. FUKUOKA; A. BABA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

Simple Synthetic Method of Allyl-and Vinyl-Epoxides by Allylation of Carbonyl Groups with Allylic Tins Catalyzed by PbI 2 -HMPA. -The PbI 2 -HMPA catalyzed chemoselective carbonyl-allylation in α-halo ketones to achieve one-pot preparation of allyl epoxides (III) is presented. Moreover a simple and