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ChemInform Abstract: Efficient Synthesis of Biaryls Through the Kumada Reaction Catalyzed by Carbene Adducts of Cyclopalladated Ferrocenylimine.

✍ Scribed by Gerui Ren; Xiuling Cui; Yangjie Wu


Publisher
John Wiley and Sons
Year
2010
Weight
97 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The novel ferrocene‐Pd‐carbene catalyst allows the preparation of a variety of biaryls and polyarylalkenes in high yields from aryl bromides and chlorides.


πŸ“œ SIMILAR VOLUMES


Efficient Synthesis of Biaryls through t
✍ Gerui Ren; Xiuling Cui; Yangjie Wu πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 258 KB

## Abstract A series of carbene adducts of cyclopalladated ferrocenylimine were prepared and evaluated in the cross‐coupling reaction of aryl halides with Grignard reagents (the Kumada reaction). Complex **d** exhibited high catalytic activity for the coupling of aryl chlorides with sterically hind