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An Efficient Catalyst for the Synthesis of ortho-Substituted Biaryls by the Suzuki Cross-Coupling: Triphenylphosphine Adduct of Cyclopalladated Ferrocenylimine.

✍ Scribed by Hong Li; Yangjie Wu; Weibo Yan

Publisher
John Wiley and Sons
Year
2007
Weight
24 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract **Incredible Bulk**: A series of N‐heterocyclic carbene catalysts (see picture) were prepared and evaluated in the Suzuki–Miyaura reaction. A variety of sterically encumbered tetra‐__ortho__‐substituted biaryl products were formed from unreactive aryl chlorides using the isopentyl‐subst

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