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ChemInform Abstract: Efficient Generation of β-L-Rhamnosidic Linkages via the Ulosyl Bromide Approach.

✍ Scribed by F. W. LICHTENTHALER; T. W. METZ


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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Glycosylation via Locked Anomeric Configuration: Stereospecific Synthesis of Oligosaccharides Containing the β-D-Mannopyranosyl and β-L-Rhamnopyranosyl Linkage. -cis-1,2-Stannylene acetals derived from D-mannose and L-rhamnose are capable of displacing the triflyl leaving groups in carbohydrates to