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ChemInform Abstract: Efficient Copper-Catalyzed Direct Amination of Aryl Halides Using Aqueous Ammonia in Water.

✍ Scribed by Fei Meng; Xinhai Zhu; Ying Li; Jianwei Xie; Bo Wang; Junhua Yao; Yiqian Wan

Publisher
John Wiley and Sons
Year
2011
Weight
30 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The easy availability of the ligand, the commercially available cheap copper source, the use of a green solvent and aqueous ammonia as the readily available nitrogen source are features of this protocol.

πŸ“œ SIMILAR VOLUMES

Efficient Copper-Catalyzed Direct Aminat
Efficient Copper-Catalyzed Direct Amination of Aryl Halides Using Aqueous Ammonia in Water
✍ Fei Meng; Xinhai Zhu; Ying Li; Jianwei Xie; Bo Wang; Junhua Yao; Yiqian Wan πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 324 KB

## Abstract The __N^2^,N^2^β€²__‐diisopropyloxalohydrazide/CuO system efficiently catalyzed the direct amination of aryl bromides andiodides with aqueous ammonia in water at 60 Β°C in 24 h or at 120 Β°C in only 20–30 min. Both activated and unactivated aryl and heteroaryl bromides and iodides were read