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ChemInform Abstract: Efficient Borylation of Reactive Aryl Halides with MPBH (4,4,6-Trimethyl-1,3,2-dioxaborinane).

✍ Scribed by Nageswaran PraveenGanesh; Emilien Demory; Christine Gamon; Veronique Blandin; Pierre Y. Chavant

Publisher
John Wiley and Sons
Year
2011
Weight
29 KB
Volume
42
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Improved Preparatio
ChemInform Abstract: Improved Preparation of 4,6,6-Trimethyl-1,3,2-dioxaborinane and Its Use in a Simple [PdCl2(TPP)2]-Catalyzed Borylation of Aryl Bromides and Iodides.
✍ Nageswaran PraveenGanesh; Pierre Yves Chavant πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons βš– 42 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Improved Preparation of 4,6,6-Trimethyl-
Improved Preparation of 4,6,6-Trimethyl-1,3,2-dioxaborinane and Its Use in a Simple [PdCl2(TPP)2]-Catalyzed Borylation of Aryl Bromides and Iodides
✍ Nageswaran PraveenGanesh; Pierre Yves Chavant πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 233 KB

## Abstract We describe a convenient preparation of 4,6,6‐trimethyl‐1,3,2‐dioxaborinane (MethylPentaneDiolBorane, MPBH) and demonstrate that it is an excellent reagent for the [PdCl~2~(PPh~3~)~2~]‐catalyzed borylation of aryl bromides and iodides. The corresponding boronic esters undergo rapid Suzu