4,4,6-Trimethyl-1,3,2-dioxaborinane: A Practical Reagent for Palladium-Catalyzed Borylation of Aryl Halides.
β Scribed by Miki Murata; Takeshi Oda; Shinji Watanabe; Yuzuru Masuda
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 27 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract We describe a convenient preparation of 4,6,6βtrimethylβ1,3,2βdioxaborinane (MethylPentaneDiolBorane, MPBH) and demonstrate that it is an excellent reagent for the [PdCl~2~(PPh~3~)~2~]βcatalyzed borylation of aryl bromides and iodides. The corresponding boronic esters undergo rapid Suzu
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