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ChemInform Abstract: Effect of Crown Ethers on the Regioselectivity of Allylation of Benzaldehyde with Allylic Barium Reagents.

โœ Scribed by A. YANAGISAWA; Y. YAMADA; H. YAMAMOTO

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Phosphine-Directed
ChemInform Abstract: Phosphine-Directed Stereo- and Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers.
โœ M. T. DIDIUK; J. P. MORKEN; A. H. HOVEYDA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 39 KB

Phosphine-Directed Stereo-and Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers. -In the presence of a properly positioned internal Lewis base like a phosphine unit various acyclic and cyclic allylic ethers are regio-and stereoselectively methylated or phenylated. Under