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ChemInform Abstract: Easy Access to α-Bromoketones and Epoxides from vic-Dibromides under Aqueous Conditions.

✍ Scribed by Rajendra D. Patil; Subbarayappa Adimurthy; Brindaban C. Ranu

Publisher
John Wiley and Sons
Year
2011
Weight
25 KB
Volume
42
Category
Article
ISSN
0931-7597

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The title method for the synthesis of acetophenones of type (III), obtained in fair to good yields, is a good alternative to organometallic reactions. Lithium chloride, generated by deprotonation of the phosphonium salt with PhLi as base, probably acts as a Lewis acid to activate the nitrile functio