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ChemInform Abstract: Dynamic Kinetic Resolution of α-Keto Esters via Asymmetric Transfer Hydrogenation.

✍ Scribed by Kimberly M. Steward; Emily C. Gentry; Jeffrey S. Johnson

Book ID
115553035
Publisher
John Wiley and Sons
Year
2012
Weight
30 KB
Volume
43
Category
Article
ISSN
0931-7597

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Hydrogen transfer reduction of a-sulfonylaldehydes using HCOOH-Et 3 N system as hydrogen source and (S,S)-TsDPEN-based Ru(II) as catalyst proceeds with dynamic kinetic resolution, providing optically active b-sulfonyl primary alcohols in moderate-to-good yields and up to 90% ee.