The sense and level of 1,2-asymmetric induction have been evaluated in the BF3.OEI ~ promoted addition of (E)crotylsilanes (R)-I and (S)-I to or-amino aldehydes 2a through 2d. The sense of carbonyl diastereoface selectivity was shown to be dependent of the chirality of the silane reagent.
ChemInform Abstract: Double Stereodifferentiating Crotylation Reactions with α-Amino Aldehydes: Asymmetric Synthesis of Vicinal Amino Alcohol Synthons.
✍ Scribed by J. S. PANEK; P. LIU
- Book ID
- 101854212
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v