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ChemInform Abstract: Dirhodium(II) Tetrakis(N-phthaloyl-(S)-tert-leucinate): A Notable Catalyst for Enantiotopically Selective Aromatic Substitution Reactions of α-Diazocarbonyl Compounds.

✍ Scribed by N. WATANABE; T. OGAWA; Y. OHTAKE; S. IKEGAMI; S. HASHIMOTO


Book ID
112031415
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
27
Category
Article
ISSN
0931-7597

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Dirhodium(II) tetrakis[N-tetrafluorophth
✍ Hideyuki Tsutsui; Yukiko Yamaguchi; Shinji Kitagaki; Seiichi Nakamura; Masahiro 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 200 KB

Dirhodium(II) tetrakis[N-tetrafluorophthaloyl-(S)-tert-leucinate], Rh 2 [(S)-TFPTTL] 4 , in which the phthalimido hydrogen atoms of the parent dirhodium(II) complex are substituted by fluorine atoms, dramatically enhances the reactivity and enantioselectivity (up to 97% ee) in intramolecular aromati