ChemInform Abstract: Directed Deprotonation—Transmetalation as a Route to Substituted Pyridines.
✍ Scribed by Gunter Karig; James A. Spencer; Timothy Gallagher
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Directed Methallylations as a Synthetic Route to 1,3-Polyols. -Methallylboronic acid (II), applied as freshly prepared solution, reacts with βhydroxyketones (I) to produce the 1,3-diols (III) with good diastereoselectivity. Only the relatively small ethyl group gives poor selectivity. However, simi
Deprotonation of Benzyl Isothiocyanate: A Simple Route to Silylated Benzyl Isothiocyanates. -A new and convenient one-pot synthesis of mono-(III) and bis(silyl)benzyl isothiocyanates via lithiated benzyl isothiocyanates is developed.