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ChemInform Abstract: Direct Vinylation of 2-Substituted N-(Benzylidene)glycinonitriles under Basic Conditions.

✍ Scribed by A. JONCZYK; Z. PAKULSKI

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Direct Vinylation of 2-Substituted N-(Benzylidene)glycinonitriles under Basic Conditions.

-Ξ±-Vinyl substituted nitriles (III), (V), and (VI) are prepared via addition of carbanions generated from nitriles (I) to acetylenes ( II) and (IV). However, all attempts to convert these products into . beta.,Ξ³-unsaturated Ξ±-amino acids fail. Only Ξ±,Ξ² -unsaturated ketones, e.g. (VII), are obtained. -(JONCZYK, A.;

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