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ChemInform Abstract: Cleavage of the N—O Bond in Substituted Hydroxylamines under Basic Conditions.

✍ Scribed by Kirill V. Nikitin; Nonna P. Andryukhova

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
31
Category
Article
ISSN
0931-7597

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Direct Vinylation of 2-Substituted N-(Benzylidene)glycinonitriles under Basic Conditions. -α-Vinyl substituted nitriles (III), (V), and (VI) are prepared via addition of carbanions generated from nitriles (I) to acetylenes ( II) and (IV). However, all attempts to convert these products into . beta.