ChemInform Abstract: Dimorphism of K4Ta2S11: Syntheses, Crystal Structures, and Properties of Two Alkali Metal Tantalum Sulfides.
β Scribed by Sabine Herzog; Christian Naether; Wolfgang Bensch
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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for (II) (500 Β°C, 6 d). (I) crystallizes in the orthorhombic space group Pnma with Z = 4. Its structure consists of isolated tetrahedral [TaS4] 3-anions, and Rb + and Ba 2+ cations. The Ba 2+ cations are surrounded by nine S atoms forming distorted tricapped trigonal prisms, whereas the Rb + cations
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