ChemInform Abstract: Diastereoselective Simmons—Smith Cyclopropanations of Allylic Amines and Carbamates.
✍ Scribed by Stephen G. Davies; Kenneth B. Ling; Paul M. Roberts; Angela J. Russell; James E. Thomson
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 39 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Asymmetric Simmons-Smith Cyclopropanation of α,β-Unsaturated Bornane-2,3-diol Acetals. -Reaction of selected α,β-unsaturated aldehydes (II) with bornanediol (I) affords novel chiral acetals (III), which undergo diastereoselective cyclopropanation with a Simmons-Smith reagent giving compounds (V). -
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