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ChemInform Abstract: Diastereoselective Radical Alkylations of Alkyl Aryl Sulfoxides.

✍ Scribed by M. ZAHOUILY; G. CARON; P.-A. CARRUPT; N. KNOUZI; P. RENAUD

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

1997 sulfoxides, sulfones, sulfenes and derivatives sulfoxides, sulfones, sulfenes and derivatives (benzene compounds) Q 0600 10 -087 Diastereoselective Radical Alkylations of Alkyl Aryl Sulfoxides.

-The radical alkylations of sulfoxides (I) with the stannane (II) is investigated. Thus, the use of the ortho-chlorophenyl sulfinyl group allows anti-stereoselective alkylation whereas bulkier R1-groups lead to cis-selectivity. -(ZAHOUILY,

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