Diastereoselective Cyclopropanation of α,β-Unsaturated Acetals of a Novel Camphor-Derived Chiral Auxiliary. -2-exo-3-exo-Dihydroxybornane-10-sulfonate (III) proves to be a highly efficient chiral auxiliary for the asymmetric Simmons-Smith cyclopropanation of α,βunsaturated acetal derivatives [cf.
ChemInform Abstract: Diastereoselective Baylis—Hillman Reactions: The Design and Synthesis of a Novel Camphor-Based Chiral Auxiliary.
✍ Scribed by Kung-Shuo Yang; Kwunmin Chen
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract The DABCO‐catalyzed reaction of allenoate (I), bearing a chiral auxiliary on the ester moiety, with sulfonylimines (II) affords the title products.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v