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ChemInform Abstract: Diastereoselective Aza-Baylis—Hillman Reactions: Synthesis of Chiral α-Allenylamines and 2-Azetines from Allenic Esters.

✍ Scribed by Bruna S. Santos; Ana L. Cardoso; Ana Matos Beja; Manuela Ramos Silva; Jose A. Paixao; Francisco Palacios; Teresa M. V. D. Pinho e Melo

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201044029

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✦ Synopsis

Abstract

The DABCO‐catalyzed reaction of allenoate (I), bearing a chiral auxiliary on the ester moiety, with sulfonylimines (II) affords the title products.

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