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ChemInform Abstract: Diastereoselective Addition of Chiral (2-Lithiophenyl)acetaldehyde Acetals to Various Imines as Key Step in the Asymmetric Synthesis of 1-Aryltetrahydroisoquinolines. Part 4.

✍ Scribed by Bernhard Wuensch; Sven Nerdinger

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199925129

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Diastereoselective Addition of Chiral (2-Lithiophenyl)acetaldehyde Acetals to Various Imines as Key Step in the Asymmetric Synthesis of 1-Aryltetrahydroisoquinolines, Part 4

✍ Bernhard Wünsch; Sven Nerdinger 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 354 KB 👁 1 views

A novel asymmetric synthesis of 1-aryl-1,2,3,4-tetrahy-sodium in liquid ammonia and ammonium cerium(IV) nitrate, respectively, to yield the primary amines 35 and 36. The acid-droisoquinolines has been developed. The key step in this synthesis is the diastereoselective addition of homochiral (2-catal

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ChemInform Abstract: Asymmetric Synthesis of 1-Aryl-1,2,3,4-tetrahydroisoquinolines. Part 3. Investigation of the Diastereoselectivity During the Addition of an Enantiomerically Pure (2-Lithiophenyl)acetaldehyde Acetal to Various Imines.

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