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ChemInform Abstract: Desymmetrization of meso-2-Alkene-1,4-diol Derivatives Through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes.

✍ Scribed by Hajime Ito; Takuma Okura; Kou Matsuura; Masaya Sawamura

Publisher: John Wiley and Sons
Year: 2010
Weight: 76 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201021026

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Desymmetrization of meso-2-Alkene-1,4-di

Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes

✍ Hajime Ito; Takuma Okura; Kou Matsuura; Masaya Sawamura 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 336 KB 👁 1 views

Desymmetrization reactions of meso compounds through enantioselective catalysis are a powerful strategy for the synthesis of chiral molecules with multiple stereocenters. One well-known example is the Pd-catalyzed desymmetrization of meso-2-alkene-1,4-diol derivatives (Trosts Pd-catalyzed asymmetric

Desymmetrization of meso-2-Alkene-1,4-di

Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes

✍ Hajime Ito; Takuma Okura; Kou Matsuura; Masaya Sawamura 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 336 KB 👁 2 views