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ChemInform Abstract: Design, Construction and Properties of Peptide N-Terminal Cap Templates Devised to Initiate α-Helices. Part 2. Caps Derived from N-[(2S)-2-Chloropropionyl]-(2S)-Pro-(2S)-Pro-(2S,4S)-4-thioPro-OMe.

✍ Scribed by Arwel Lewis; John Wilkie; Trevor J. Rutherford; David Gani

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199914229

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✦ Synopsis

Design, Construction and Properties of Peptide N-Terminal Cap Templates Devised to Initiate α-Helices. Part 2. Caps Derived from N-[(2S)-2-Chloropropionyl]-(2S)-Pro-(2S)-Pro-(2S,4S)-4-thioPro-OMe.

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ChemInform Abstract: Design, Synthesis, Structure and Properties of an α-Helix Cap Template Derived from N-[(2S)-2-Chloropropionyl]-(2S)-Pro-(2R)-Ala-(2S,4S)-4-thioPro-OMe which Initiates α-Helical Structures.

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Design, Synthesis, Structure and Properties of an α-Helix Cap Template Derived from N-[(2S)-2-Chloropropionyl]-(2S)-Pro-(2R)-Ala-(2S,4S)-4-thioPro-OMe which Initiates α-Helical Structures. -Each amide bond of the 12-membered macrocyclic template, derived from the title peptide, exists in the trans-r