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ChemInform Abstract: Deoxyxylothymidine 3′-O-Phosphorothioates: Synthesis, Stereochemistry and Stereocontrolled Incorporation into Oligothymidylates.

✍ Scribed by X. YANG; K. MISIURA; M. SOCHACKI; W. J. STEC


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Convenient Synthesi
✍ W. KUDELSKA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 2 views

Convenient Synthesis of S-and Se-(2,3,4,6-Tetra-O-benzyl-Dglucopyranosyl)-phosphorothioate, Phosphoroselenoate and Phosphorodithioate. -BF 3 -mediated reaction of both 1-O-unprotected and 1-O-acyl sugars (I) with phosphorothioate (II), -selenate (IV) or -dithiolate (VI) provides the corresponding g