ChemInform Abstract: Dehydrochlorination Reactions of Substituted 1,1,1-Trichloro-2,2- diarylethanes. Mechanisms and Reagents
β Scribed by S. G. SIBRIKOV; V. N. KAZIN; V. V. KOPEIKIN
- Book ID
- 112025548
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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In the base-promoted dehydrochlorinT;ion of I.i-dichloro-2,2-diphenyiethane-l-C and its D-nitro analog, the isotope effects, k/ k, are 1.045 and 1.024, respectively. These results support an.Elcb-like E2 mechanism for both elimination reactions.
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## Abstract The reaction substrate (I) with various arenes is mediated by BF~3~Β·Et~2~O or TFA with comparable yields.