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ChemInform Abstract: Darzens Reaction of Acyl Phosphonates with α-Bromo Ketones: Selective Synthesis of cis- and trans-Epoxyphosphonates.

✍ Scribed by Ayhan S. Demir; Mustafa Emrullahoglu; Eser Pirkin; Nazmiye Akca


Publisher
John Wiley and Sons
Year
2009
Weight
35 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Reaction of Monocar
✍ M. OCHIAI; Y. KITAGAWA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

Reaction of Monocarbonyl Iodonium Ylides with Activated Imines: Stereoselective Synthesis of trans-and cis-α,β-Aziridino Ketones. -Treatment of iodonium salts (I) with lithium ethoxylate generates monocarbonyl iodonium ylides which readily undergo alkylidene-transfer reactions with activated imines.