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ChemInform Abstract: Cyclopropenation of Alkylidene Carbenes Derived from α-Silyl Ketones.

✍ Scribed by Jingwei Li; Chunrui Sun; Daesung Lee

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
41
Category
Article
ISSN
0931-7597

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✍ H. SHINOKUBO; K. OSHIMA; K. UTIMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Facile Syntheses of α-Bromo-α-silyl Ketones and α-Bromoacylsilanes from tert-Butyldimethylsilyldibromomethane and Carbonyl Compounds. -The synthesis of title compounds such as (III) and (V) and their usefulness is shown. The Tbs-group plays a critical role in the formation of these products. Mechan