ChemInform Abstract: Cyclopropanation of Phenyl Styryl Sulfones with Phenacylsulfonium Ylides under Phase-Transfer Catalysis.
β Scribed by A. PADMAJA; K. R. REDDY; V. PADMAVATHI; D. B. REDDY
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Cyclopropanation of Phenyl Styryl Sulfones with Phenacylsulfonium Ylides under Phase-Transfer Catalysis. -The title reaction results in the stereoselective formation of cyclopropanes (III) (12 examples). This phase transfer catalyzed reaction proves to be more facile and efficient than direct addition of ylides to sulfones (I). Several of the obtained cyclopropane derivatives show promising antimicrobial activity. -(PADMAJA, A.; REDDY, K.
π SIMILAR VOLUMES
Direct Dichlorovinylation of Nitriles with Trichloroethylene under Phase-Transfer Catalysis Conditions. -The methodology opens a convenient way for the preparation of dichlorovinyl-substituted nitriles (11 examples) under optimized conditions. Cleavage of these products bearing Ξ±-heteroatoms gives
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