ChemInform Abstract: Direct Dichlorovinylation of Nitriles with Trichloroethylene under Phase-Transfer Catalysis Conditions.

✍ Scribed by A. JONCZYK; A. H. GIERCZAK

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 34 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199843096

✦ Synopsis

Direct Dichlorovinylation of Nitriles with Trichloroethylene under Phase-Transfer Catalysis Conditions.

-The methodology opens a convenient way for the preparation of dichlorovinyl-substituted nitriles (11 examples) under optimized conditions. Cleavage of these products bearing α-heteroatoms gives an easy access to the corresponding ketones [cf. (VI)].