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ChemInform Abstract: Cyclopentadienylthallium(I) as a Ligand Transfer Reagent

✍ Scribed by C. JANIAK

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
29
Category
Article
ISSN
0931-7597

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The [Re(CO) 6 ] + cation is a stable compound, soluble in aqueous media. We show that it can be used as a reagent in the synthesis of tricarbonyl(cyclopentadienyl)rhenium complexes. [Re(CO) 6 ] + reacts with ferrocene derivatives, particularly acetylferrocene, in DMSO, DMF or a water/DMSO (1:1)